The Raman Scattering of Uranyl and Transuranium V, VI, and VII Ions-Reference-Cited by-同舟云学术

The Raman Scattering of Uranyl and Transuranium V, VI, and VII Ions

Published:1974-03 Issue:2 Volume:28 Page:142-145
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Basile L. J.¹,Sullivan J. C.¹,Ferraro J. R.¹,LaBonville P.¹

Affiliation:

1. Argonne National Laboratory, Argonne, Illinois 60439

Abstract

The Raman scattering of U(VI), Np(VI), Pu(VI), Am(VI), and Np(V), Am(V) in HClO4 solutions and Np(VII) in a NaOH medium is reported. Direct observation of the polarized ν1 vibration (D∞h symmetry) is observed for the transuranium MO2n+ ions in the V and VI oxidation states. The spectroscopic evidence is consistent with a linear MO2n+ structure for the Np(VII) ion in basic solutions. The trend of the ν1 frequency and the MO stretching force constants with the oxidation is discussed and is correlated with the bond strengths and the stability of the MO2n+ ions.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/000370274774332812

Reference27 articles.

1. Infrared Spectra and Structure of the Crystalline Sodium Acetate Complexes of U(VI), Np(VI), Pu(VI), and Am(VI). A Comparison of Metal‐Oxygen Bond Distance and Bond Force Constant in this Series

2. Raman and infrared spectroscopic studies of the uranyl ion: the symmetric stretching frequency, force constants, and bond lengths

3. Infra-Red Spectra of Uranyl Compounds. I. Uranyl Nitrates

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