Determination of Total Chlorine in Chrysotile by X-ray Fluorescence Spectrometry

Author:

Zamojska Régina1,Sharman Jeff1,Cote Yvon1,Jolicoeur Carmel1

Affiliation:

1. Département de Chimie, Université de Sherbrooke, Sherbrooke, Québec J1K 2R1, Canada

Abstract

Energy-dispersive x-ray spectrometric methods have been developed for the determination of chlorine in asbestos (chrysotile) fibers. Chlorine, which is a minor constituent, is determined by a standard addition method from the ground fiber and by a standardless method in six different fibers. The lower limit of detection for a qualitative analysis and the lower limit of determination for a quantitative analysis of chlorine in the asbestos matrix are 40 ppm and 120 ppm, respectively. The water-soluble and acid-soluble chlorine have also been determined by ion-exchange chromatography and by a colorimetric method. The agreement of the three different methods is very good in all cases.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference13 articles.

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2. Jeffrey P. G., Chemical Methods of Rock Analysis (Pergamon Press, New York, 1970), pp. 184–188.

3. The chlorine and fluorine contents of geochemical standards

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