A New Line-Narrowing Procedure Based on Fourier Self-Deconvolution, Maximum Entropy, and Linear Prediction

Author:

Kauppinen J. K.1,Moffatt D. J.1,Hollberg M. R.1,Mantsch H. H.1

Affiliation:

1. Department of Physical Sciences, University of Turku, Vesilinnantie 5, SF-20500 Turku, Finland (J.K.K., M.R.H.); and Steacie Institute for Molecular Sciences, National Research Council, Ottawa, Ontario K1A 0R6, Canada (D.J.M., H.H.M.)

Abstract

We propose a new methodology to reduce the widths of spectral lines. This procedure, which is performed entirely in the time domain, combines elements of the methods of Fourier Self-Deconvolution (FSD), Maximum Entropy (MEM), and Linear Prediction (LP) in such a way as to take advantage of the efficacies of each of these procedures. The procedure is illustrated with examples.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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