Affiliation:
1. Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, Quebec H3A 2K6, Canada
Abstract
Gas-phase IR photoacoustic (PA) spectra have been obtained for the volatile, solid pentacarbonyl(methyl)metal(I) complexes, CH3Mn(CO)5 and CH3Re(CO)5. The gaseous samples were apparently produced directly in the PA sample cup as the result of local surface heating effects. Vibrational assignments are given for the gas-phase spectra, especially for the binary v(CO) overtone and combinations which absorb in the near-IR region at ∼4000 cm−1. The data provide further support for near-IR/PA spectroscopy being a useful technique for the rapid, nondestructive identification of small amounts of organometallic carbonyl complexes.
Subject
Spectroscopy,Instrumentation
Cited by
5 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献