Affiliation:
1. Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, Quebec H3A 2K6, Canada
Abstract
Solid-state mid- and near-IR photoacoustic (PA) spectra have been measured at room temperature for the group 6B metal(0) mixed carbonyl- t-butylisocyanide complexes M(CO)6- n(CN tBu) n ( M = Cr, Mo, W; n = 1-3). Vibrational assignments are proposed for many of the observed bands. The PA spectra in the near-IR region (4600-3600 cm−1), where the binary v(CN) and v(CO) overtones and combinations absorb, are useful spectral fingerprints for these organometallic complexes.
Subject
Spectroscopy,Instrumentation
Cited by
3 articles.
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