Affiliation:
1. Analytical Sciences Laboratories, 1897 Building, The Dow Chemical Company, Midland, Michigan 48667
Abstract
Hydrogen bonding, dielectric effects, and steric effects are all factors which determine the carbonyl stretching frequency, vC=O, of ketones in solution. The vC=O frequency for ketones shifts continuously at constant concentration in solutions of CHCl3/CCl4 with change in the mole ratio of the two solvents. The vC=O frequency is also affected by change in concentration in either CCl4 or CHCl3 solution.
Subject
Spectroscopy,Instrumentation
Cited by
43 articles.
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