A Study for N2 Coherent Anti-Stokes Raman Spectroscopy Thermometry at High Pressure

Author:

Kataoka Haruhiko1,Maeda Shiro1,Hirose Chiaki1,Kajiyama Koichi1

Affiliation:

1. Research Laboratory of Resources Utilization Tokyo Institute of Technology, 4259 Nagatsuta-cho Midori-ku, Yokohama, 227 Japan (U.K., S.M., C.H.) and Technical Research Center, Komatsu Ltd., 2597 Shinomiya Hiratsuka, Kanagawa, 254 Japan

Abstract

N2 coherent anti-Stokes Raman spectroscopy (CARS) thermometry over a pressure range 1 to 50 atm has been studied. The CARS profile at high pressure and high temperature was recorded by using the ignition inside a running engine cylinder. The observed Q-branch profile was theoretically fitted by incorporating the collisional narrowing effect, serving for the temperature determination at various pressures. Because of the narrowing effect, the apparent band width showed little change with pressure above 5 atm in general. It has been suggested that the band width at 1/5 of the maximum height can be a useful measure of temperature, while the usual half-width turns out to be hardly practicable at high pressures.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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