Rydberg series of CO in the region 14—20 eV

Author:

Shan Xiao-Bin ,Zhang Jie ,Sheng Liu-Si ,Wang Si-Sheng ,Zhang Li-Hua ,Zhao Yu-Jie ,Hao Li-Qing ,Wang Zhen-Ya , , , , ,

Abstract

Absolute photoabsorption spectrum of CO molecule in the region 14—20 eV(620—890 Å) is measured using synchrotron radiation and multi-stage photoionization chamber, and its ionization energy is obtained. According to the absorption spectrum of CO and theoretical calculation, the Rydberg series converging to the Χ2Σ+, Α2Π, and B2Σ+ states of CO+ are assigned separately. Rydberg series assigned before are extended, Rydberg series converging to the Χ2Σ+ (ν+=2 and 3) of CO+, and n=2 (the real value of n is 3) progressions of the series converging to the Α2Π state of CO+ are identified. At the same time, the absorption spectrum of CO in the region 17.0—17.5 eV (710—730 Å) is also discussed deeply.

Publisher

Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences

Subject

General Physics and Astronomy

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