Orientation-independent room temperature optical 13 C hyperpolarization in powdered diamond

Author:

Ajoy Ashok1,Liu Kristina1,Nazaryan Raffi1,Lv Xudong1,Zangara Pablo R.2ORCID,Safvati Benjamin3ORCID,Wang Guoqing14ORCID,Arnold Daniel1,Li Grace1ORCID,Lin Arthur1ORCID,Raghavan Priyanka1,Druga Emanuel1,Dhomkar Siddharth2ORCID,Pagliero Daniela2ORCID,Reimer Jeffrey A.5ORCID,Suter Dieter6ORCID,Meriles Carlos A.27,Pines Alexander1ORCID

Affiliation:

1. Department of Chemistry, and Materials Science Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, Berkeley, CA 94720, USA.

2. Department of Physics, City University of New York (CUNY)–City College of New York, New York, NY 10031, USA.

3. Department of Physics, University of California, Berkeley, Berkeley, CA 94720, USA.

4. Department of Physics, Peking University, Beijing, China.

5. Department of Chemical and Biomolecular Engineering, and Materials Science Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, Berkeley, CA 94720, USA.

6. Fakultät Physik, Technische Universität Dortmund, D-44221 Dortmund, Germany.

7. CUNY–Graduate Center, New York, NY 10016, USA.

Abstract

Shining light on diamond particles makes them MRI-“bright,” opening avenues for room temperature hyperpolarized liquids.

Funder

National Science Foundation

Research Corporation for Science Advancement

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference41 articles.

1. R. Ernst G. Bodenhausen A.Wokaun Principles of Nuclear Magnetic Resonance in One and Two Dimensions (Clarendon Press Oxford 1987).

2. NMR studies of structure and function of biological macromolecules (Nobel Lecture);Wüthrich K.;Angew. Chem. Int. Ed.,2003

3. Principles of dynamic nuclear polarisation

4. Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR

5. Dynamic nuclear polarization at high magnetic fields;Maly T.;J. Chem. Phys.,2008

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