Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites

Author:

Wu Xiaoxi1,Tan Liang Z.2,Shen Xiaozhe3,Hu Te4,Miyata Kiyoshi5ORCID,Trinh M. Tuan5,Li Renkai3,Coffee Ryan3ORCID,Liu Shi6,Egger David A.7,Makasyuk Igor3,Zheng Qiang3,Fry Alan3,Robinson Joseph S.3,Smith Matthew D.8,Guzelturk Burak1,Karunadasa Hemamala I.8,Wang Xijie3,Zhu Xiaoyang5ORCID,Kronik Leeor7,Rappe Andrew M.2,Lindenberg Aaron M.149ORCID

Affiliation:

1. Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA.

2. The Makineni Theoretical Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104–6323, USA.

3. SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA.

4. Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305, USA.

5. Department of Chemistry, Columbia University, New York, NY 10027, USA.

6. Extreme Materials Initiative, Geophysical Laboratory, Carnegie Institution for Science, Washington, DC 20015, USA.

7. Department of Materials and Interfaces, Weizmann Institute of Science, Rehovoth 76100, Israel.

8. Department of Chemistry, Stanford University, Stanford, CA 94305, USA.

9. PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA.

Abstract

Absorption of light in hybrid perovskite solar cells leads to ultrafast large-amplitude deformations of the inorganic sublattice.

Funder

Office of Naval Research

Basic Energy Sciences

National Science Foundation

Alfred P. Sloan Foundation

Austrian Science Fund

Precourt Institute for Energy Sciences

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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