Gigantic Photoresponse in ¼-Filled-Band Organic Salt (EDO-TTF) 2 PF 6

Author:

Chollet Matthieu12345,Guerin Laurent12345,Uchida Naoki12345,Fukaya Souichi12345,Shimoda Hiroaki12345,Ishikawa Tadahiko12345,Matsuda Kazunari12345,Hasegawa Takumi12345,Ota Akira12345,Yamochi Hideki12345,Saito Gunzi12345,Tazaki Ryoko12345,Adachi Shin-ichi12345,Koshihara Shin-ya12345

Affiliation:

1. Department of Materials Science, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro-ku, Tokyo 152-8551, Japan.

2. Groupe Matière Condensée et Matériaux, Centre National de la Recherche Scientifique, Unite Mixte de Recherche-6626, Université de Rennes 1, Rennes, France.

3. Kanagawa Academy of Science and Technology and Japan Science and Technology Agency (JST), Precursory Research for Embryonic Science and Technology (PRESTO), 3-2-1, Sakado, Takatsu-ku, Kawasaki 213-0012, Japan.

4. Department of Physics, Tokyo Institute of Technology, Japan.

5. Division of Chemistry, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.

Abstract

We report that the organic salt (EDO-TTF) 2 PF 6 with ¾-filled-band (¼-filled in terms of holes), which forms an organic metal with strong electron and lattice correlation, shows a highly sensitive response to photoexcitation. An ultrafast, photoinduced phase transition from the insulator phase to the metal phase can be induced with very weak excitation intensity at near room temperature. This response makes the material attractive for applications in switching devices with room-temperature operation. The observed photo-induced spectroscopic change shows that this photoinduced phase transition process is caused by the cooperative melting of charge ordering assisted by coherent phonon generation.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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