Carrier lifetimes of >1 μs in Sn-Pb perovskites enable efficient all-perovskite tandem solar cells

Author:

Tong Jinhui12ORCID,Song Zhaoning3ORCID,Kim Dong Hoe1ORCID,Chen Xihan1ORCID,Chen Cong3ORCID,Palmstrom Axel F.1ORCID,Ndione Paul F.1ORCID,Reese Matthew O.1ORCID,Dunfield Sean P.124ORCID,Reid Obadiah G.12ORCID,Liu Jun1ORCID,Zhang Fei1ORCID,Harvey Steven P.1ORCID,Li Zhen1ORCID,Christensen Steven T.1ORCID,Teeter Glenn1ORCID,Zhao Dewei3ORCID,Al-Jassim Mowafak M.1,van Hest Maikel F. A. M.1ORCID,Beard Matthew C.1ORCID,Shaheen Sean E.25ORCID,Berry Joseph J.1ORCID,Yan Yanfa3ORCID,Zhu Kai1ORCID

Affiliation:

1. National Renewable Energy Laboratory, Golden, CO 80401, USA.

2. Renewable and Sustainable Energy Institute, University of Colorado, Boulder, CO 80309, USA.

3. Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, University of Toledo, Toledo, OH 43606, USA.

4. Materials Science and Engineering Program, University of Colorado, Boulder, CO 80309, USA.

5. Department of Electrical, Computer and Energy Engineering, University of Colorado, Boulder, CO 80309, USA.

Abstract

Efficient all-perovskite tandem cells Organic-inorganic perovskite films can boost the output of conventional silicon solar cells in tandem geometries by utilizing more of the light at the blue end of the solar spectrum. Tandem cells that use only perovskite films have been less successful because of the lack of a suitable material with a low bandgap that can replace silicon. Tong et al. report that a mixed tin-lead organic-inorganic material containing a small fraction of guanidinium thiocyanate has a low bandgap, long charge-carrier lifetime, and efficiencies around 25%. Science , this issue p. 475

Funder

U.S. Department of Energy

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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