Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere-Reference-Cited by-同舟云学术

Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere

Published:2023-12-15 Issue:6676 Volume:382 Page:1308-1314
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

He Xu-Cheng¹²³^ORCID,Simon Mario⁴^ORCID,Iyer Siddharth⁵^ORCID,Xie Hong-Bin⁶^ORCID,Rörup Birte¹^ORCID,Shen Jiali¹,Finkenzeller Henning⁷⁸^ORCID,Stolzenburg Dominik¹⁹^ORCID,Zhang Rongjie⁶,Baccarini Andrea¹⁰¹¹^ORCID,Tham Yee Jun¹¹²^ORCID,Wang Mingyi¹³^ORCID,Amanatidis Stavros¹³^ORCID,Piedehierro Ana A.³,Amorim Antonio¹⁴^ORCID,Baalbaki Rima¹^ORCID,Brasseur Zoé¹^ORCID,Caudillo Lucía⁴^ORCID,Chu Biwu¹¹⁵^ORCID,Dada Lubna¹¹⁰^ORCID,Duplissy Jonathan¹¹⁶^ORCID,El Haddad Imad¹⁰^ORCID,Flagan Richard C.¹³^ORCID,Granzin Manuel⁴,Hansel Armin¹⁷^ORCID,Heinritzi Martin⁴^ORCID,Hofbauer Victoria²^ORCID,Jokinen Tuija¹¹⁸^ORCID,Kemppainen Deniz¹^ORCID,Kong Weimeng¹³^ORCID,Krechmer Jordan¹⁹^ORCID,Kürten Andreas⁴^ORCID,Lamkaddam Houssni¹⁰,Lopez Brandon²²⁰,Ma Fangfang⁶^ORCID,Mahfouz Naser G. A.²,Makhmutov Vladimir²¹²²^ORCID,Manninen Hanna E.²³^ORCID,Marie Guillaume⁴^ORCID,Marten Ruby¹⁰^ORCID,Massabò Dario²⁴^ORCID,Mauldin Roy L.²⁵²⁶^ORCID,Mentler Bernhard¹⁷^ORCID,Onnela Antti²³^ORCID,Petäjä Tuukka¹^ORCID,Pfeifer Joschka²³,Philippov Maxim²¹^ORCID,Ranjithkumar Ananth²⁷,Rissanen Matti P.⁵²⁸^ORCID,Schobesberger Siegfried²⁹^ORCID,Scholz Wiebke¹⁷^ORCID,Schulze Benjamin¹³^ORCID,Surdu Mihnea¹⁰,Thakur Roseline C.¹^ORCID,Tomé António³⁰^ORCID,Wagner Andrea C.⁴^ORCID,Wang Dongyu¹⁰^ORCID,Wang Yonghong¹¹⁵^ORCID,Weber Stefan K.⁴²³^ORCID,Welti André³^ORCID,Winkler Paul M.³¹,Zauner-Wieczorek Marcel⁴^ORCID,Baltensperger Urs¹⁰^ORCID,Curtius Joachim⁴^ORCID,Kurtén Theo²⁸,Worsnop Douglas R.¹¹⁹^ORCID,Volkamer Rainer⁷⁸^ORCID,Lehtipalo Katrianne¹³^ORCID,Kirkby Jasper⁴²³^ORCID,Donahue Neil M.²²⁰²⁵³²^ORCID,Sipilä Mikko¹^ORCID,Kulmala Markku¹¹⁶³³³⁴^ORCID

Affiliation:

1. Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland.

2. Center for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

3. Finnish Meteorological Institute, 00560 Helsinki, Finland.

4. Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany.

5. Aerosol Physics Laboratory, Faculty of Engineering and Natural Sciences, Tampere University, 33720 Tampere, Finland.

6. Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, 116024 Dalian, China.

7. Department of Chemistry, University of Colorado Boulder, Boulder, CO 80309, USA.

8. Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO 80309, USA.

9. Institute for Materials Chemistry, TU Wien, 1060 Vienna, Austria.

10. Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, CH-5232 Villigen, Switzerland.

11. Laboratory of Atmospheric Processes and their Impact, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland.

12. School of Marine Sciences, Sun Yat-sen University, 519082 Zhuhai, China.

13. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA.

14. CENTRA and Faculdade de Ciências da Universidade de Lisboa, 1749-016 Lisboa, Portugal.

15. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 100084 Beijing, China.

16. Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki, Finland.

17. Institute of Ion Physics and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria.

18. Climate and Atmosphere Research Centre (CARE-C), The Cyprus Institute, 1645 Nicosia, Cyprus.

19. Aerodyne Research, Inc., Billerica, MA 01821, USA.

20. Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

21. P. N. Lebedev Physical Institute of the Russian Academy of Sciences, 119991 Moscow, Russia.

22. Moscow Institute of Physics and Technology (National Research University),141701 Moscow, Russian Federation.

23. CERN, the European Organization for Nuclear Research, CH-1211 Geneva, Switzerland.

24. Department of Physics, University of Genoa, 16146 Genoa, Italy.

25. Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

26. Department of Atmospheric and Oceanic Sciences, University of Colorado Boulder, Boulder, CO 80309, USA.

27. Natural Environment Research Council, British Antarctic Survey, CB3 0ET Cambridge, UK.

28. Department of Chemistry, University of Helsinki, 00014 Helsinki, Finland.

29. Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland.

30. Instituto Dom Luiz (IDL)–Universidade da Beira Interior, 6201-001 Covilhã, Portugal.

31. Faculty of Physics, University of Vienna, 1090 Wien, Austria.

32. Department of Engineering and Public Policy, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

33. Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, 210023 Nanjing, China.

34. Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, 100029 Beijing, China.

Abstract

The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H 2 SO 4 ), stabilized by ammonia (NH 3 ). However, in marine and polar regions, NH 3 is generally low, and H 2 SO 4 is frequently found together with iodine oxoacids [HIO x , i.e., iodic acid (HIO 3 ) and iodous acid (HIO 2 )]. In experiments performed with the CERN CLOUD (Cosmics Leaving OUtdoor Droplets) chamber, we investigated the interplay of H 2 SO 4 and HIO x during atmospheric particle nucleation. We found that HIO x greatly enhances H 2 SO 4 (-NH 3 ) nucleation through two different interactions. First, HIO 3 strongly binds with H 2 SO 4 in charged clusters so they drive particle nucleation synergistically. Second, HIO 2 substitutes for NH 3 , forming strongly bound H 2 SO 4 -HIO 2 acid-base pairs in molecular clusters. Global observations imply that HIO x is enhancing H 2 SO 4 (-NH 3 ) nucleation rates 10- to 10,000-fold in marine and polar regions.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Link

https://www.science.org/doi/pdf/10.1126/science.adh2526

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