Spectroscopic Observation of the Formyl Cation in a Condensed Phase-Reference-Cited by-同舟云学术

Spectroscopic Observation of the Formyl Cation in a Condensed Phase

Published:1997-05-02 Issue:5313 Volume:276 Page:776-779
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

de Rege Peter J. F.¹²,Gladysz John A.¹²,Horváth István T.¹²

Affiliation:

1. P. J. F. de Rege and I. T. Horváth, Corporate Research Laboratories, Exxon Research and Engineering Company, Annandale, NJ 08801, USA.

2. J. A. Gladysz, Department of Chemistry, University of Utah, Salt Lake City, UT 84112, USA.

Abstract

The formyl cation, HCO + , has long been believed to be an important intermediate in the chemistry of carbon monoxide (CO) in acidic environments, but its spectroscopic observation in solution has been elusive. This species was generated by the reaction of CO with the liquid superacid hydrofluoric acid–antimony pentafluoride (HF-SbF 5 ) under pressure and was observed by nuclear magnetic resonance and infrared spectroscopy. Equilibria between CO in the gas phase, CO dissolved in HF-SbF 5 , the SbF 5 adduct of formyl fluoride, and HCO + associated with several equilibrating anions of the type [Sb x F 5 x +1 ] − are proposed to describe the system.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference61 articles.

1. J. March Advanced Organic Chemistry (Wiley-Interscience New York 1992).

2. D. Bethell in Comprehensive Organic Chemistry D. Barton and W. D. Ollis Eds. (Pergamon New York 1979) vol. 1 pp. 411–453; H. Heaney ibid. pp. 241–360.

3. N. C. Price and L. Steven Fundamentals of Enzymology (Oxford Univ. Press Oxford 1982) pp. 157-158

4. B. C. Gates Catalytic Chemistry (Wiley New York 1992) chap. 3;

5. Thauer R. K., Angew. Chem. Int. Ed. Engl. 34, 2247 (1995).

Cited by 53 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The Oxocarbenium Ion Intermediate;Comprehensive Glycoscience;2021

2. Metal‐free Carbon Monoxide (CO) Capture and Utilization: Formylation of Amines;Advanced Synthesis & Catalysis;2019-04-12

3. Constructing organic superacids from superhalogens is a rational route as verified by DFT calculations;Physical Chemistry Chemical Physics;2019

4. Combining proton and silaborane-based superhalogen anions – an effective route to new superacids as verified via systematic DFT calculations;Dalton Transactions;2019

5. Festschrift in Honor of István T. Horváth;ACS Sustainable Chemistry & Engineering;2018-08-06