Combining proton and silaborane-based superhalogen anions – an effective route to new superacids as verified via systematic DFT calculations
Author:
Affiliation:
1. MOE Key Laboratory of Synthetic and Natural Functional Molecule Chemistry
2. College of Chemistry and Materials Science
3. Northwest University
4. Xi'an 710069
5. China
Abstract
Based on systematic DFT calculations, silaborane-based superhalogen anions, which obey the Wade–Mingos rule, are shown to be capable of giving rise to superacids via their combination with protons.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Shaanxi Province
Northwest University
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03616D
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