Comment on “Cycling Li-O 2 batteries via LiOH formation and decomposition”-Reference-Cited by-同舟云学术

Comment on “Cycling Li-O 2 batteries via LiOH formation and decomposition”

Published:2016-05-06 Issue:6286 Volume:352 Page:667-667
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Shen Yue¹,Zhang Wang¹,Chou Shu-Lei²,Dou Shi-Xue²

Affiliation:

1. State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China.

2. Institute for Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Innovation Campus, Squires Way, North Wollongong NSW 2522, Australia.

Abstract

Liu et al . (Research Article, 30 October 2015, p. 530) described a lithium-oxygen (Li-O 2 ) battery based on lithium iodide (LiI)–assisted lithium hydroxide (LiOH) formation and decomposition. We argue that LiOH cannot be oxidized by triiodide (I 3 – ). The charge capacity is from the oxidation of I – instead of LiOH. The limited-capacity cycling test is misleading when the electrolyte contributes considerable parasitic reaction capacity.

Funder

Natural Science Foundation of China

Australian Research Council

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference7 articles.

1. Cycling Li-O 2 batteries via LiOH formation and decomposition

2. The effects of moisture contamination in the Li-O2 battery

3. Li–O2 and Li–S batteries with high energy storage

4. Aprotic and Aqueous Li–O2 Batteries

5. Aqueous Lithium/Air Rechargeable Batteries

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