Spaceborne detection of localized carbon dioxide sources

Abstract

INTRODUCTION Although the carbon budget is often presented in terms of global-scale fluxes, many of the contributing processes occur through localized point sources, which have been challenging to measure from space. Persistent anthropogenic carbon dioxide (CO 2 ) emissions have altered the natural balance of Earth’s carbon sources and sinks. These emissions are driven by a multitude of individual mobile and stationary point sources that combust fossil fuels, with urban areas accounting for more than 70% of anthropogenic emissions to the atmosphere. Natural point-source emissions are dominated by wildfires and persistent volcanic degassing. RATIONALE Comprehensive global measurements from space could help to more completely characterize anthropogenic and natural point-source emissions. In global carbon cycle models, anthropogenic point-source information comes from bottom-up emission inventories, whereas natural point-source information comes from a sparse in situ measurement network. Whereas clusters of urban CO 2 point-source plumes merge together, isolated point sources (e.g., remote power plants, cement production plants, and persistently degassing volcanoes) create localized plumes. Because turbulent mixing and diffusion cause rapid downwind dilution, they are challenging to detect and analyze. Point-source detection from space is complicated by signal dilution: The observed values of Δ X CO 2 (enhancement of the column-averaged dry-air CO 2 mole fraction) correspond to in situ CO 2 enhancements of 10-fold or higher. Space-based sensors that detect and quantify CO 2 in plumes from individual point sources would enable validation of reported inventory fluxes for power plants. These sensors would also advance the detectability of volcanic eruption precursors and improve volcanic CO 2 emission inventories. RESULTS Spaceborne measurements of atmospheric CO 2 using kilometer-scale data from NASA’s Orbiting Carbon Observatory-2 (OCO-2) reveal distinct structures caused by known anthropogenic and natural point sources, including megacities and volcanoes. Continuous along-track sampling across Los Angeles (USA) by OCO-2 at its ~2.25-km spatial resolution exposes intra-urban spatial variability in the atmospheric X CO 2 distribution that corresponds to the structure of the urban dome, which is detectable under favorable wind conditions. Los Angeles X CO 2 peaks over the urban core and decreases through suburban areas to rural background values more than ~100 km away. Enhancements of X CO 2 in the Los Angeles urban CO 2 dome observed by OCO-2 vary seasonally from 4.4 to 6.1 parts per million (ppm). We also detected isolated CO 2 plumes from the persistently degassing Yasur, Ambrym, and Aoba volcanoes (Vanuatu), corroborated by near-simultaneous sulfur dioxide plume detections by NASA’s Ozone Mapping and Profiler Suite. An OCO-2 transect passing directly downwind of Yasur volcano yielded a narrow filament of enhanced X CO 2 ( Δ X CO 2 ≈ 3.4 ppm), consistent with plume modeling of a CO 2 point source emitting 41.6 ± 19.7 kilotons per day (15.2 ± 7.2 megatons per year). These highest continuous volcanic CO 2 emissions are collectively dwarfed by about 70 fossil fuel–burning power plants on Earth, which each emit more than 15 megatons per year of CO 2 . CONCLUSION OCO-2’s sampling strategy was designed to characterize CO 2 sources and sinks on regional to continental and ocean-basin scales, but the unprecedented kilometer-scale resolution and high sensitivity enables detection of CO 2 from natural and anthropogenic localized emission sources. OCO-2 captures seasonal, intra-urban, and isolated plume signals. Capitalizing on OCO-2’s sensitivity, a much higher temporal resolution would capture anthropogenic emission signal variations from diurnal, weekly, climatic, and economic effects, and, for volcanoes, precursory emission variability. Future sampling strategies will benefit from a continuous mapping approach with the sensitivity of OCO-2 to systematically and repeatedly capture these smaller, urban to individual plume scales of CO 2 point sources. OCO-2 detects urban CO 2 signals with unprecedented detail over Los Angeles. Individual “footprints” of OCO-2 X CO 2 data from early fall 2014 and summer 2015 over the city of Los Angeles strongly contrast with values over the distant, rural Antelope Valley. X CO 2 is the averaged dry-air molar CO 2 concentration between the spacecraft and Earth’s surface.