Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction-Reference-Cited by-同舟云学术

Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction

Published:2017-07-28 Issue:6349 Volume:357 Page:389-393
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Yao Siyu¹^ORCID,Zhang Xiao²^ORCID,Zhou Wu³⁴^ORCID,Gao Rui⁵⁶,Xu Wenqian⁷^ORCID,Ye Yifan⁸,Lin Lili¹^ORCID,Wen Xiaodong⁵⁶,Liu Ping⁷^ORCID,Chen Bingbing²^ORCID,Crumlin Ethan⁸^ORCID,Guo Jinghua⁸^ORCID,Zuo Zhijun⁹,Li Weizhen¹,Xie Jinglin¹^ORCID,Lu Li¹⁰^ORCID,Kiely Christopher J.¹⁰^ORCID,Gu Lin¹¹^ORCID,Shi Chuan²^ORCID,Rodriguez José A.⁷^ORCID,Ma Ding¹^ORCID

Affiliation:

1. College of Chemistry and Molecular Engineering and College of Engineering, Peking University, Beijing 100871, China.

2. State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, Dalian 116024, China.

3. School of Physical Sciences, CAS (Chinese Academy of Sciences) Key Laboratory of Vacuum Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.

4. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

5. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Post Office Box 165, Taiyuan, Shanxi 030001, China.

6. Synfuels China, Beijing 100195, China.

7. Chemistry Division, Building 555, Brookhaven National Laboratory, Post Office Box 5000, Upton, NY 11973-5000, USA.

8. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

9. Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China.

10. Department of Materials Science and Engineering, Lehigh University, Bethlehem, PA 18015-3195, USA.

11. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.

Abstract

Low-temperature CO removal Carbon monoxide deactivates fuel cell catalysts, so it must be removed from H 2 generated from hydrocarbons on site. Yao et al. developed a catalyst composed of layered gold clusters on molybdenum carbide (MoC) nanoparticles to convert CO through its reaction with water into H 2 and CO 2 at temperatures as low as 150°C. Water was activated on MoC to form surface hydroxyl groups, which then reacted with CO adsorbed on the gold clusters. Science , this issue p. 389

Funder

National Natural Science Foundation of China

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference38 articles.

1. Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts

2. Activity of CeO x and TiO x Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction

3. Water-Gas Shift Reaction on a Highly Active Inverse CeOx/Cu(111) Catalyst: Unique Role of Ceria Nanoparticles

4. Alkali-Stabilized Pt-OH x Species Catalyze Low-Temperature Water-Gas Shift Reactions

5. Catalytically active Au-O(OH) x - species stabilized by alkali ions on zeolites and mesoporous oxides

Cited by 600 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Metal edge confined platinum atoms in metal/hydroxide hierarchy structure for multiple hydrogen conversion and evolution;Applied Catalysis B: Environment and Energy;2024-12

2. CO2 hydrogenation to methanol on efficient Pd modified α-MoC1−x catalysts;Fuel;2024-11

3. Effect of transition metals (Ni and Co) in the methanol oxidation reaction electrocatalytic activity on Mo2C/MWCNT;Molecular Catalysis;2024-10

4. A comprehensive analysis of a compact-sized methanol cracking unit for hydrogen production;International Journal of Hydrogen Energy;2024-10

5. Pt Atom-Substituted MoC Single-Atom Catalyst for Enhancing H₂ Production;ACS Catalysis;2024-09-12