Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol-Reference-Cited by-同舟云学术

Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol

Published:2020-01-10 Issue:6474 Volume:367 Page:193-197
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Jin Zhu¹²^ORCID,Wang Liang¹^ORCID,Zuidema Erik³^ORCID,Mondal Kartick⁴^ORCID,Zhang Ming⁵^ORCID,Zhang Jian²^ORCID,Wang Chengtao²,Meng Xiangju²,Yang Hengquan⁵,Mesters Carl⁶,Xiao Feng-Shou¹²^ORCID

Affiliation:

1. Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.

2. Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, China.

3. Shell Global Solutions International B.V., 1031HW Amsterdam, Netherlands.

4. Shell India Markets Pvt. Ltd., Shell Technology Centre, Plot 7, Bangalore Hardware Park, Devanahalli Industrial Area, Bangalore 562149, India.

5. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China.

6. Shell International Exploration and Production, Houston, TX 77082, USA.

Abstract

Confining peroxide to make methanol In principle, hydrogen peroxide would be an efficient oxidant for the conversion of methane to methanol under mild conditions. In practice, however, it is currently too expensive to produce the peroxide ahead of time for this purpose. Jin et al. report a catalyst system that generates and concentrates hydrogen peroxide for immediate reaction with methane. A hydrophobically coated zeolite keeps the peroxide close to the gold and palladium active site, where incoming methane is then selectively oxidized to methanol. Science , this issue p. 193

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Shell Global Solutions B. V.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference52 articles.

1. Platinum Catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative

2. Aqueous Au-Pd colloids catalyze selective CH 4 oxidation to CH 3 OH with O 2 under mild conditions

3. Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles