Aqueous Au-Pd colloids catalyze selective CH 4 oxidation to CH 3 OH with O 2 under mild conditions-Reference-Cited by-同舟云学术

Aqueous Au-Pd colloids catalyze selective CH 4 oxidation to CH 3 OH with O 2 under mild conditions

Published:2017-10-13 Issue:6360 Volume:358 Page:223-227
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Agarwal Nishtha¹^ORCID,Freakley Simon J.¹^ORCID,McVicker Rebecca U.¹^ORCID,Althahban Sultan M.²^ORCID,Dimitratos Nikolaos¹^ORCID,He Qian¹^ORCID,Morgan David J.¹^ORCID,Jenkins Robert L.¹^ORCID,Willock David J.¹^ORCID,Taylor Stuart H.¹,Kiely Christopher J.¹²^ORCID,Hutchings Graham J.¹^ORCID

Affiliation:

1. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK.

2. Department of Materials Science and Engineering, Lehigh University, 5 East Packer Avenue, Bethlehem, PA 18015, USA.

Abstract

A radical route from methane to methanol The conversion of methane into chemicals usually proceeds through high-temperature routes that first form more reactive carbon monoxide and hydrogen. Agarwal et al. report a low-temperature (50°C) route in aqueous hydrogen peroxide (H 2 O 2 ) for oxidizing methane to methanol in high yield (92%). They used colloidal gold-palladium nanoparticles as a catalyst. The primary oxidant was O 2 ; isotopic labeling showed that H 2 O 2 activated methane to methyl radicals, which subsequently incorporated O 2 . Science , this issue p. 223

Funder

National Science Foundation

Cardiff University

Saudi Arabian government-Jazan University

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference32 articles.

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