Bio-oil From Coconut Fibers: Fractionation by Preparative Liquid Chromatography for Phenols Isolation

Author:

Farrapeira Rafael de Oliveira1,Andrade Yasmine B1,Conrado Nathalia Mendonça1,Schneider Jaderson Kleveston2ORCID,Krause Laiza Canielas3,Caramão Elina Bastos1

Affiliation:

1. Universidade Tiradentes

2. Universidade Federal do Pampa - Campus Sao Gabriel

3. Federal University of Sergipe: Universidade Federal de Sergipe

Abstract

Abstract The great potential of bio-products generated from agro-industrial residues from the biomass processing, as is the case of the green coconut fibers (Cocos nucifera L. var. dwarf), makes that Brazil stands out in the field of transformation of these residues, mainly due to its high biodiversity and favorable climatic conditions. In this work, residual green coconut fibers were used in the production of bio-oil by pyrolysis. The bio-oil was fractionated using preparative liquid chromatography in silica (PLC) using solvents at different polarities. Bio-oil and its fractions were analyzed by GC/qMS. PLC of bio-oil increased the number of compounds identified by about 170% compared to the original bio-oil (non-fractionated), besides allowing the isolation of nonpolar compounds (mostly hydrocarbons), from polar compounds (mainly phenols, aldehydes and ketones). Among the compounds, phenols can be highlighted, besides furfural derivatives and hydrocarbons, which indicates the potential use of bio-oil mainly for industrial purposes.

Publisher

Research Square Platform LLC

Reference25 articles.

1. Aboulkas A, Hammani H, Achaby ME, Bila E, Barakat A, Harfi KE (2017) Valorization of Algal Waste via Pyrolysis in a Fixed-Bed Reactor: Production and Characterization of Bio-Oil and Bio-Char Bioresour. Technol. 1016/j.biortech.2017.06.098

2. Phenolic compounds: Current industrial applications, limitations and future challenges;Albuquerque BR;Food Funct,2021

3. Recovery of waste biomass: pyrolysis and characterization of sugarcane residues and their bio-oils;Barros JA;Biofuels,2021

4. The effect of the biomass components lignin, cellulose and hemicellulose on TGA and fixed bed pyrolysis;Burhenne L;J Anal Appl Pyr,2013

5. Fractionation and extraction of bio-oil for production of greener fuel and value-added chemicals: recent advances and future prospects;Chan YH;Chem Eng J,2020

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3