A mathematical model of the current density distribution in electrochemical cells

Author:

Popov Konstantin1,Zivkovic Predrag2,Nikolic Nebojsa3

Affiliation:

1. Faculty of Technology and Metallurgy, Belgrade + ICTM - Institute of Electrochemistry, Belgrade

2. Faculty of Technology and Metallurgy, Belgrade

3. ICTM - Institute of Electrochemistry, Belgrade

Abstract

An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.

Publisher

National Library of Serbia

Subject

General Chemistry

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