Organic-inorganic membranes for filtration of corn distillery

Abstract

Organic-inorganic membranes were obtained by modification of polymer microfiltration membrane with inorganic ion-exchangers, which form secondary porosity inside macroporous substrate (zirconium hydrophosphate) or simultaneously in the macroporous substrate and active layer, depending of the particle size (from ?50 nm up to several microns). Precipitation of the inorganic constituent is considered from the point of view of Ostwald-Freundlich equation. Such processes as pressing test in deionized water and filtration of corn distillery at 1-6 bar were investigated. Theoretical model allowing to establish fouling mechanism, was applied. It was found that the particles both in the substrate and active layer prevent fouling of the membrane with organics and provide rejection of colloidal particles.