Spectrophotometric investigations of the reaction between gold(III) and potassium iodide

Author:

Vasic Vesna1,Premovic Suzana1,Cakar Mira2,Radak Bojan1ORCID,Milovanovic Gordana3

Affiliation:

1. Vinča Institute of Nuclear Sciences, Belgrade

2. Faculty of Pharmacy, Belgrade

3. Faculty of Chemistry, Belgrade

Abstract

The equilibria of the complex formation between AuCl4-n(OH)n - and I- was studied spectrophotometrically in aqueous solutions containing KI:Au(III)?2 in the acidity range from 1 M HCl to pH 7 at 25?C. From the hydrogen ion and Cl-ion dependence of the absorption spectra, it was found that AuCl2I2 - and Au(OH)2I2 - complexes were formed. The equilibrium constants of complex formation were determined.

Publisher

National Library of Serbia

Subject

General Chemistry

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