Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst-Reference-Cited by-同舟云学术

Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst

Published:2011 Issue:1 Volume:43 Page:55-62
ISSN:0350-820X
Container-title:Science of Sintering
language:en
Short-container-title:SCI SINTER

Author:

Maksimovic J.P.¹,Cupic Z.D.²,Loncarevic D.²,Pejic N.³,Vasiljevic-Radovic D.⁴,Anic S.²

Affiliation:

1. Faculty of Physical Chemistry, Belgrade

2. IChTM - Center of Catalysis and Chemical Engineering, Belgrade

3. Faculty of Pharmacy, Belgrade

4. IChTM - Center of Microelectronic Technologies and Single Crystals, Belgrade

Abstract

The Bray-Liebhafsky (BL) oscillatory reaction generated in the batch reactor at 62- 68 oC was perturbed by cobalt(II)-nitrate, supported on the macroreticular copolymer of poly-4-vinylpyridine with divinylbenzene (Co-PVPDVB). The kinetic data was analyzed of the complex pathways of the hydrogen peroxide decomposition in the examined BL reaction. The obtained results confirm that the kinetics of the BL reaction in the presence Co-PVPDVB comes partially from the Co-catalyst and partially from the macroreticular copolymer support.

Publisher

National Library of Serbia

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,Ceramics and Composites

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