Enthalpies of mixing in binary Fe–Sb, Ce–Fe and ternary Ce–Fe–Sb liquid alloys-Reference-Cited by-同舟云学术

Enthalpies of mixing in binary Fe–Sb, Ce–Fe and ternary Ce–Fe–Sb liquid alloys

Published:2016-01-08 Issue:1 Volume:107 Page:13-20
ISSN:2195-8556
Container-title:International Journal of Materials Research
language:en
Short-container-title:

Author:

Usenko Natalia¹,Kotova Natalia¹,Ivanov Michael²,Berezutski Vadim²

Affiliation:

1. Department of Chemistry , Taras Shevchenko National University, Kyiv , Ukraine

2. I. Frantsevich Institute for Problems of Materials Science , National Academy of Sciences, Kyiv , Ukraine

Abstract

Abstract The enthalpies of mixing in liquid alloys in the binary Fe–Sb, Ce–Fe and ternary Ce–Fe–Sb systems were determined over a wide range of composition by means of isoperibolic calorimetry in the temperature range 1600–1830 K. The minimum values of the integral enthalpy of mixing (ΔH min) were determined to be (−2.32 ± 0.22) kJ · mol−1 at x Sb = 0.5 in the Fe–Sb system, and (−0.97 ± 0.19) kJ · mol−1 at x Ce = 0.35 in the Ce–Fe system. The enthalpies of mixing in liquid ternary Ce–Fe–Sb alloys were found to increase smoothly from the binary boundary systems Ce–Fe and Fe–Sb towards the Ce–Sb system, reaching the minimum value of (−107.5 ± 3.6) kJ · mol−1 in the vicinity of the phase CeSb.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

Link

https://www.degruyter.com/document/doi/10.3139/146.111319/pdf

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