Mixing enthalpies in binary Ce-Sb and ternary Ce-Co-Sb liquid alloys-Reference-Cited by-同舟云学术

Mixing enthalpies in binary Ce-Sb and ternary Ce-Co-Sb liquid alloys

Published:2013-01-01 Issue:1 Volume:104 Page:46-50
ISSN:2195-8556
Container-title:International Journal of Materials Research
language:
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Author:

Usenko Natalia¹,Kotova Natalia¹,Ivanov Michael²,Berezutski Vadim²

Affiliation:

1. a Department of Chemistry, Taras Shevchenko National University, Kyiv, Ukraine

2. b I. Frantsevich Institute for Problems of Materials Science, National Academy of Sciences, Kyiv, Ukraine

Abstract

AbstractThe enthalpies of mixing in liquid alloys in the binary Ce-Sb and ternary Ce-Co-Sb systems were determined over a wide range of composition by means of isoperibolic calorimetry in the temperature range 1 600-1 723 K. The minimum value of the integral enthalpy of mixing (ΔHmin) in the Ce-Sb system was evaluated to be −123 kJ mol-1 at xCe = 0.55. The enthalpies of mixing in liquid ternary alloys were found to increase smoothly from the binary boundary systems Co-Ce and Co-Sb towards the Ce-Sb system reaching the value of approximately −123 kJ mol-1 in the vicinity of the phase CeSb.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

Link

https://www.degruyter.com/document/doi/10.3139/146.110834/pdf

Reference14 articles.

1. Mixing enthalpies of liquid Co–Ce and Co–Sm alloys

2. The Au−Mo (Gold-Molybdenum) system

3. Structural and thermodynamic data on the pseudobinary phases R(Co1−xCux)5 WITH R ≡ Sm, Y, Ce

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