Best Combination of Promoter and Micellar Catalyst for Room Temperature Rapid Conversion of D-Lyxose to D-Lyxonic Acid in Aqueous Medium

Abstract

AbstractThe kinetic study of catalytic oxidation of D-lyxose by hexavalent chromium has been investigated spectrophotometrically under pseudo first order condition at temperature 313 K. The rate of oxidation of D-lyxose is very slow. Picolinic acid (PA), 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) are used as promoter to accelerate the rate of the reaction. Phen acts as the most effective promoter in aqueous medium. The rate of the reaction is also increased in presence of nonionic surfactant Triton-X-100 (TX-100) and anionic surfactant sodium dodecyl sulphate (SDS). They are used as catalyst in this reaction. Thus the observed micellar effects have been explained by considering the hydrophobic and electrostatic interactions between the reactants and surfactants in terms of the proposed mechanism. However, the combination of promoter and surfactants produces a better result. The maximum rate enhancement is obtained in presence of the combination of phen and TX-100.