Extraction of Natural Surfactant Saponin from Soapnut (Sapindus mukorossi) and its Utilization in the Remediation of Hexavalent Chromium from Contaminated Water

Abstract

AbstractIn this study optimization of extraction conditions for saponin from soapnut (Sapindus mukorossi) has been investigated. This investigation showed that a better extraction of saponin can be achieved with increasing the dielectric constant of solvent employed. The best yield was attained in a 50% v/v aqueous ethanol medium. Another objective of the present study is to assess the thermodynamics of the uptake-reduction of hexavalent chromium in contaminated water samples using saponin. Pyrene has been employed to determine the critical micellar concentration (CMC) (in the UV-vis method of determination) of saponin as a spectroscopic probe. Thus, the effectiveness of the bio-surfactant as a self-motivated adsorbent for hexavalent chromium is investigated. Several physico-chemical parameters like contact time, sorbate concentration, pH and temperature have been determined. The findings of the investigation invoked a very efficient uptake of 213.48 mg g−1 of hexavalent chromium from the contaminated water sample at a lower value of pH 2 and temperature 35°C. It is observed that the method followed a pseudo-first order kinetics, where the evaluated ΔG0 has supported the sorption as a feasible and spontaneous process. The HR-MS, FTIR, steady state Fluorescence spectroscopy, HR-TEM and UV-Vis spectroscopy have been employed for the current scientific studies.