Author:
Jaber Sudad A.,Kyhoiesh Hussein A. K.,Jawad Sajjad H.
Abstract
Abstract
This study focuses on the synthesis of the 2-[2\-(5-bromo thiazolyl) azo]-5-di-methyl amino benzoic acid (5-BrTAMB) and Cd(II) coordinate complex. Diazotization by 2-amino-5-bromo thiazole and mixation by an alkaline alcohol solution of the 3-dimethyl amino benzoic acid. Various analytical techniques, including 1H-NMR, mass spectral, FT-IR spectra, UV-Vis, elemental analysis (C.H.N.S), measurement of electrical conductivity, magnetic susceptibility, TGA, XRD data and SEM spectra support azo ligand structures and their metal complex. The ligand is the trident N, N, O donor and forms the ML2 [metal-ligand] stoichiometry complex. Cd(II)-complex is found to have exhibited octahedral geometry. The ligand and its metal complex were screened against A. Niger for their antifungal activity and antibacterial activity against S. Aurores and E. Coli.
Subject
General Physics and Astronomy
Reference32 articles.
1. Enaminones - Assisted Synthesis of Disperse Dyes. Part 1: Low Temperature Dyeing of Polyester Fabrics;Elapasery;Egy. J. Chem.,2020
2. Synthesis and structure of a novel hetarylazoindole dye studied by X-ray diffraction, FT-IR, FT-Raman, UV–vis, NMR spectra and DFT calculations;Aktan;J. Mol. Struct.,2011
3. Determination of naturally occurring resveratrol analog trans-4, 4′-dihydroxystilbene in rat plasma by liquid chromatography-tandem mass spectrometry: application to a pharmacokinetic study;Chen;Anal. Bioanal. Chem.,2015
4. Determination of banned azo dyes in consumer goods;Ahlström;Trends Anal. chem.,2005
5. Structure reactivity correlations of azo reactive dyes based on H-acid: I. NMR chemical shift values, pKa values, dyestuff aggregation and dyeing behaviour;Bredereck;Dyes and Pigments.,1993
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