Quantum-mechanical model of dielectric losses in nanometer layers of solid dielectrics with hydrogen bonds at ultra-low temperatures

Abstract

Abstract Upon based the finite difference methods construct the solutions for Liouville quantum kinetic equation linearized by the external field, in complex with the stationary Schrodinger equation and the Poisson operator equation, for an ensemble of non-interacting hydrogen ions (protons) migrating in the field of a crystal lattice perturbed by a variable polarizing field. The influence of the phonon subsystem is not taken into account. The equilibrium (non-balanced) proton density matrix is calculated using quantum Boltzmann statistics. The temperature spectra of dielectric losses tangent angle for hydrogen bonded crystals (HBC) in a wide temperature range (50–550 K) are calculated. At the theoretical level detected the effects of nano-crystalline states (1–10 nm) during the polarization of HBC in the region of ultra-low temperatures (4–25 K).