Epitaxial SrTiO 3 films with dielectric constants exceeding 25,000

Author:

Yang Zhifei12,Lee Dooyong1ORCID,Yue Jin1ORCID,Gabel Judith3ORCID,Lee Tien-Lin3,James Richard D.4ORCID,Chambers Scott A.5ORCID,Jalan Bharat1ORCID

Affiliation:

1. Department of Chemical Engineering and Materials Science, University of Minnesota, Twin Cities, Minneapolis, MN 55455

2. School of Physics and Astronomy, University of Minnesota, Twin Cities, Minneapolis, MN 55455

3. Diamond Light Source, Ltd., Didcot, Oxfordshire OX11 0DE, United Kingdom

4. Aerospace Engineering and Mechanics, University of Minnesota, Twin Cities, Minneapolis, MN 55455

5. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352

Abstract

Significance Semiconductor interfaces are among the most important in use in modern technology. The properties they exhibit can either enable or disable the characteristics of the materials they connect for functional performance. While much is known about important junctions involving conventional semiconductors such as Si and GaAs, there are several unsolved mysteries surrounding interfaces between oxide semiconductors. Here we resolve a long-standing issue concerning the measurement of anomalously low dielectric constants in SrTiO 3 films with record high electron mobilities. We show that the junction between doped and undoped SrTiO 3 required to make dielectric constant measurements masks the dielectric properties of the undoped film. Through modeling, we extract the latter and show that it is much higher than previously measured.

Funder

DOD | USAF | AMC | Air Force Office of Scientific Research

NSF | Directorate for Mathematical and Physical Sciences

U.S. Department of Energy

Publisher

Proceedings of the National Academy of Sciences

Subject

Multidisciplinary

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