Four-phase merging in sessile compound drops

Abstract

We consider the statics of compound droplets made of two immiscible fluids on a rigid substrate, in the limit when gravity is dominated by capillarity. In particular, we show that the merging of four phases along a single contact line is a persistent and robust phenomenon from a mechanical and thermodynamic perspective; it can and does occur for a range of interfacial energies and droplet volumes. We give an interpretation for this in the context of the macroscopic Young–Laplace law and its microscopic counterpart due to van der Waals, and show that the topological transitions that result can be of either a continuous or discontinuous type depending on the interfacial energies in question.