Anisotropic stresslet and rheology of stick–slip Janus spheres

Abstract

A Janus sphere with a stick–slip pattern can behave quite differently in its hydrodynamics compared with a no-slip or uniform-slip sphere. Here, using the Lorentz reciprocal theorem in conjunction with surface harmonic expansion, we rigorously derive the extended Faxén formula for the stresslet of a weakly stick–slip Janus sphere, capable of describing the anisotropic nature of the stresslet with an arbitrary axisymmetric stick–slip pattern in an arbitrary background flow. We find that slip anisotropy not only causes a variety of additional contributions to the stresslet, but also naturally renders a stresslet–rotation coupling that may turn a suspension of couple-free stick–slip Janus spheres into a dipolar one under the actions of an external couple. Moreover, to correctly account for the impacts of slip anisotropy on the stresslet, it is necessary to include at least the first four surface harmonic contributions. As a result, the anisotropies of both the stresslet and torque on the sphere in a linear flow field are purely reflected by a symmetric quadrupole and hexadecapole. These hydrodynamic quantities can be further mediated by an antisymmetric dipole and octupole due to the gradients of the imposed strain field. The average bulk stress and effective viscosity for a suspension of stick–slip spheres are also determined, showing characteristics quite distinct from those of a suspension of near spheres. If the spheres possess permanent dipole moments, in particular, additional stresslets and couplets can be generated by an applied external couple on each sphere and added into the bulk stress, accompanied by non-Jeffery orientational orbits of such dipolar stick–slip spheres. In addition to the above, the extended Faxén stresslet and torque relations found in this work will also provide the formulae needed for tackling problems involving hydrodynamically interacting stick–slip spheres on which small slip anisotropy may have profound impacts.