Room temperature synthesis, crystal structure and selected properties of the new compound [Mn2(bipy)4SbS4](ClO4)-Reference-Cited by-同舟云学术

Room temperature synthesis, crystal structure and selected properties of the new compound [Mn2(bipy)4SbS4](ClO4)

Published:2016-03-08 Issue:5 Volume:71 Page:395-401
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Anderer Carolin¹,Näther Christian¹,Bensch Wolfgang¹

Affiliation:

1. Institut für Anorganische Chemie , Christian-Albrechts-Universität zu Kiel , Max-Eyth-Straße 2, 24118 Kiel, Germany

Abstract

Abstract The new compound [Mn2(bipy)4SbS4](ClO4) was prepared by a new synthetic route for the preparation of thioantimonates(V) that can be used even at room temperature. Mixing aqueous solutions of [Mn(bipy)3](ClO4)2 and Na3SbS4 · 9H2O leads to immediate crystallization of the pure compound. In the structure an SbS4 3– anion acts as a tetradentate bridge connecting two Mn2+ cations of [Mn(bipy)3]2+ complexes (bipy = 2,2′-bipyridine). The compound features a hitherto unknown [Mn2(bipy)4SbS4]+ cation. Bipy ligands of adjacent cations are arranged parallel to each other leading to weak off-center parallel π-π interactions stabilizing the crystals. Magnetic measurements indicate weak antiferromagnetic exchange interactions between the Mn2+ centers.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2015-0205/pdf

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