The cation and anion bonding modes make a difference: an unprecedented layered structure and a tri(hetero)nuclear moiety in thioantimonates(v)-Reference-Cited by-同舟云学术

The cation and anion bonding modes make a difference: an unprecedented layered structure and a tri(hetero)nuclear moiety in thioantimonates(v)

Published:2021 Issue:48 Volume:50 Page:18107-18117
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Danker Felix¹,Engesser Tobias A.¹,Broich Dario¹,Näther Christian¹^ORCID,Bensch Wolfgang¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Christian-Albrechts-University of Kiel, Max-Eyth-Str. 2, 24118 Kiel, Germany

Abstract

Mixing solutions of M2+ (M = Cu2+ or Zn2+) salts containing cyclam as ligand and an aqueous solution of Na3SbS4·9H2O led to crystallization of two new compounds within minutes: {[Cu(cyclam)]3[SbS4]2}n·20nH2O and {[Zn(cyclam)]3[SbS4]2}·8H2O.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03014K

Reference77 articles.

1. �ber Tern�re Sulfide der Alkalimetalle mit Arsen und Antimon

2. Preparation, Crystal Structure, Electronic Structure, Impedance Spectroscopy, and Raman Spectroscopy of Li3SbS3and Li3AsS3

3. Na3SbS3: Single Crystal X-ray Diffraction, Raman Spectroscopy, and Impedance Measurements

4. Disorder of Cu+ in Cu3SbS3: structural investigations of the high- and low-temperature modification

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