Rational design of nanocatalysts for ambient ammonia electrosynthesis-Reference-Cited by-同舟云学术

Rational design of nanocatalysts for ambient ammonia electrosynthesis

Published:2021-06-17 Issue:0 Volume:0 Page:
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:en
Short-container-title:

Author:

Wu Limin¹²,Guo Weiwei¹²,Sun Xiaofu¹²^ORCID,Han Buxing¹²³

Affiliation:

1. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences , Institute of Chemistry, Chinese Academy of Sciences , Beijing , 100190 , China

2. School of Chemistry and Chemical Engineering , University of Chinese Academy of Sciences , Beijing , 100049 , China

3. Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering, East China Normal University , Shanghai , 200062 , China

Abstract

Abstract Ammonia (NH3) is one of the key commercial chemicals and carbon-free energy carriers. It is mainly made by Haber-Bosch process under high temperature and high pressure, which consumes huge amount of energy and releases large amounts of CO2. Developing sustainable approaches to its production is of great importance. Powered by a renewable electricity source, electrochemical N2 reduction reaction (NRR) and nitrate reduction reaction (NITRR) are potential routes to synthesize NH3 under ambient conditions. This review summarizes major recent advances in the NRR and NITRR, especially for several years. Some fundamentals for NRR and NITRR are first introduced. Afterward, the design strategies of nanocatalysts are discussed, mainly focusing on nano-structure construction/nanoconfinement, doping/defects engineering and single-atom engineering. Finally, the critical challenges remaining in this research area and promising directions for future research are discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2021-0204/pdf

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