Ketoisophorone Transformation by Marchantia polymorpha and Nicotiana tabacum Cultured Cells-Reference-Cited by-同舟云学术

Ketoisophorone Transformation by Marchantia polymorpha and Nicotiana tabacum Cultured Cells

Published:2008-06-01 Issue:5-6 Volume:63 Page:403-408
ISSN:1865-7125
Container-title:Zeitschrift für Naturforschung C
language:en
Short-container-title:

Author:

Hegazy Mohamed-Elamir F.¹,Hirata Toshifumi²,Abdel-Lateff Ahmed³,El-Razek Mohamed H. Abd⁴,Mohamed Abou El-Hamd H.⁵,Hassan Nahed M.⁶,Paré Paul W.⁷,Mahmoud Ahmed A.⁸

Affiliation:

1. Chemistry of Medicinal Plants Department, National Research Centre, Dokki, Cairo, Egypt / Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan

2. Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan

3. Department of Pharmacognosy, Faculty of Pharmacy, El-Minia University, El-Minia 61519, Egypt

4. Natural Products Chemistry Department, National Research Centre, Dokki, Cairo, Egypt

5. Department of Chemistry, Aswan-Faculty of Science, South Valley University, Aswan, Egypt

6. Hassan Chemistry of Medicinal Plants Department, National Research Centre, Dokki, Cairo, Egypt

7. Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas 79409-1061, USA

8. Department of Chemistry, Faculty of Science, El-Minia University, El-Minia 61519, Egypt

Abstract

Stereospecific olefin (C=C) and carbonyl (C=O) reduction of the readily available prochiral compound ketoisophorone (2,2,6-trimethyl-2-cyclohexene-1,4-dione) (1) by Marchantia polymorpha and Nicotiana tabacum cell suspension cultures produce the chiral products (6R)-levodione (2), (4R,5S)-4-hydroxy-3,3,5-trimethylcyclohexanone (3), and (4R,6R)-actinol (4) as well as the minor components (4R)-hydroxyisophorone (5) and (4S)-phorenol (6).

Publisher

Walter de Gruyter GmbH

Subject

General Biochemistry, Genetics and Molecular Biology

Link

https://www.degruyter.com/document/doi/10.1515/znc-2008-5-615/pdf

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