Heteronucleare Clustersysteme, XX [1] μ3-Bi8mutio-cyclo-tris(tricarbonyliridium) (3 Ir-Ir), BiIr3(CO)9 Darstellung und Strukturuntersuehung eines neuartigen Iridiumclusters / Heteronuclear Cluster Systems, X X [1] μ3-Bismutio-cyclo-tris(tricarbonyliridium)(3Ir-Ir), BiIr3(CO)9 - Synthesis and Structural Investigation of a Novel Iridium Cluster

Abstract

Abstract The synthesis of BiIr3(CO)9 is described. IR and mass spectroscopic data are discussed. The structure of BiIr3(CO)9 was solved by X-ray analysis. The structural data are discussed and compared with those of the related compounds Ir4(CO)12 and Bi[Co(CO)4]3, respectively