A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

Author:

Zhu Xiao-Hong1,Cheng Xiao-Chun1,Qian Yun-Hua1

Affiliation:

1. Jiangsu Provincial Key Laboratory of Palygorskite Science and Applied Technology , Huaiyin Institute of Technology , Huaian 223003 , P.R. China

Abstract

Abstract The neutral, four-fold protonated pyridine-3,5-dicarbox(3,5-dicarboxylatoanilide) (H4L) reacts with Mn(II) salts under hydrothermal conditions to yield a new complex: [Mn2(L)(H2O)2]·H2O (1), which has been characterized by single crystal X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 3D framework with flu (412.612.84)(46)2 topology. The magnetic properties of 1 were investigated.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Reference18 articles.

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