Synthesis and crystal structure of a new homoleptic tetraarylruthenium(IV) complex Ru(2,4,5-Me3C6H2)4-Reference-Cited by-同舟云学术

Synthesis and crystal structure of a new homoleptic tetraarylruthenium(IV) complex Ru(2,4,5-Me3C6H2)4

Published:2017-06-12 Issue:7 Volume:72 Page:523-525
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Wang Chang-Jiu¹,Wu Xiu-Li¹,Ma Xiu-Fang¹,Jia Ai-Quan¹,Zhang Qian-Feng²

Affiliation:

1. Institute of Molecular Engineering and Applied Chemistry and Anhui Province Key Laboratory of Metallurgy Engineering and Resources Recycling , Anhui University of Technology, Ma’anshan , Anhui 243002 , P.R. China

2. Institute of Molecular Engineering and Applied Chemistry and Anhui Province Key Laboratory of Metallurgy Engineering and Resources Recycling , Anhui University of Technology, Ma’anshan , Anhui 243002 , P.R. China , Fax: +86-555-2311059

Abstract

Abstract Treatment of [Ru(acac)3] (acac−=acetylacetonate) with (2,4,5-Me3C6H2)MgBr, followed by column chromatography in air, afforded the homoleptic tetraaryl-ruthenium(IV) complex [Ru(2,4,5-Me3C6H2)4] (1) in moderate yield. The product was characterized by proton NMR spectroscopy and microanalyses. Its crystal structure has also been established by X-ray crystallography.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2017-0054/pdf

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