Pushing steric limits in osmium(<scp>iv</scp>) tetraaryl complexes-Reference-Cited by-同舟云学术

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Pushing steric limits in osmium(iv) tetraaryl complexes

Published:2022 Issue:27 Volume:51 Page:10558-10570
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Parr Joseph M.¹,Olivar Clarissa¹^ORCID,Saal Thomas¹,Haiges Ralf¹^ORCID,Inkpen Michael S.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA

Abstract

Air-stable osmium(iv) tetraaryl complexes are obtained using the precursor (Oct4N)2[OsBr6] in yields of 5–73% that correlate with ligand steric bulk. Os(mesityl)4 exhibits a particularly distorted geometry and an unusual 1+/2+ solution redox feature.

Funder

University of Southern California

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01706G

Reference62 articles.

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4. Tetrahedral organic molecules as components in supramolecular architectures and in covalent assemblies, networks and polymers

5. O. M.Yaghi , M. J.Kalmutzki and C. S.Diercks , Introduction to Reticular Chemistry: Metal–Organic Frameworks and Covalent Organic Frameworks, 1st ed , Wiley Online Books; Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2019

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