Optimising coagulation/flocculation using response surface methodology and application of floc in biofertilisation

Author:

Iber Benedict Terkula12,Okomoda Victor Tosin12,Felix Gary Petol3,Abdullah Siti Rozaimah Sheikh4,Oloruntobi Olakunle5,Bokhari Awais67,Eldesoky Gaber E.8,Park Sung Jea91011,Choi Dongwhi12,Chuah Lai Fatt13,Kasan Nor Azman2

Affiliation:

1. Department of Fisheries and Aquaculture, Joseph Sarwuan Tarka University (formerly, Federal University of Agriculture Makurdi) , Makurdi , P.M.B.2373, Benue State , Nigeria

2. Higher Institution Centre of Excellence (HICoE), Institute of Tropical Aquaculture and Fisheries (AKUATROP), Universiti Malaysia Terengganu , 21030 , Kuala Nerus , Terengganu , Malaysia

3. Institute of Climate Adaptation and Marine Biotechnology (ICAMB), Universiti Malaysia Terengganu , 21030 , Kuala Nerus , Terengganu , Malaysia

4. Research Centre for Sustainable Process Technology (CESPRO), Faculty Engineering and Built Environment, Universiti Kebangsaan Malaysia , 43600 , Bangi , Selangor , Malaysia

5. Faculty of Maritime Studies, Universiti Malaysia Terengganu , Terengganu , Malaysia

6. School of Engineering, Lebanese American University , Byblos , Lebanon

7. Department of Chemical Engineering, COMSATS University Islamabad (CUI), Lahore Campus , 54000, Punjab, Lahore , Pakistan

8. Department of Chemistry, College of Science, King Saud University , P. O. Box 2455 , Riyadh , 11451 , Saudi Arabia

9. School of Mechanical Engineering, Korea University of Technology and Education , 1600 Chungjeol-ro , Cheonan , Chungnam, 31253 , South Korea

10. Advanced Technology Research Centre, Korea University of Technology and Education , 1600 Chungjeol-ro , Cheonan , Chungnam, 31253 , South Korea

11. Korea University of Technology and Education , 1600 Chungjeol-ro , Cheonan , Chungnam, 31253 , South Korea

12. Department of Mechanical Engineering (Integrated Engineering Program), Kyung Hee University , 1732 Deogyeong-daero , Yongin , Gyeonggi, 17104 , South Korea

13. School of Technology Management and Logistics, Universiti Utara Malaysia , 06010 , Sintok , Kedah Darul Aman , Malaysia

Abstract

Abstract Aquaculture effluent generation, an environmentally crucial process requires effective treatment. Simple methods like coagulation and flocculation are considered effective. In this study, chitosan from Black tiger shrimp, Penaeus monodon, was used to remove ammonia (NH3) and turbidity. Response surface methodology-optimised dosages (5.00, 12.50, and 20.00 mg·L−1), pH (5.00, 6.25, and 7.50), and settling times (5.00, 7.50, and 30.00 min) were applied. Water spinach, Ipomea aquatica, received an application for organic fertiliser after the nutrient status of the recovered floc was later determined. Results showed that at a dose of 16.25 mg·L−1, a pH of 7.5, and a settling time of 17.5 min, chitosan cleared 92.16% of the turbidity. After 30 min of settling, 84.42% of the NH3 was eliminated at 5 mg·L−1 and 7.5 pH. Both macronutrients (P, K, N, Mg, and Ca) and micronutrients (Co, Cu, Fe, Mn, Ni, Se, and Zn) are present in the newly discovered floc. Floc had safe low Pb and Ni levels. Plants treated with floc showed superior growth compared to those with commercial liquid fertiliser, confirming nutrient absorbability. Conclusively, this study provides an eco-friendly wastewater treatment method.

Publisher

Walter de Gruyter GmbH

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