Zur Reaktion von Carben-Addukten des Kohlenstoffdisulfids mit Brom und Iod [1] / On the Reaction of Carbene Adducts of Carbon Disulfide with Bromine and Iodine [1]-Reference-Cited by-同舟云学术

Zur Reaktion von Carben-Addukten des Kohlenstoffdisulfids mit Brom und Iod [1] / On the Reaction of Carbene Adducts of Carbon Disulfide with Bromine and Iodine [1]

Published:1994-11-01 Issue:11 Volume:49 Page:1473-1480
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Kuhn Norbert¹,Bohnen Hans¹,Henkel Gerald²

Affiliation:

1. Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen

2. Fachbereich 6 (Chemie) der Universität (GH) Duisburg, Lotharstraße 1, D-47048 Duisburg

Abstract

Abstract The carbene adducts 3 are obtained as stable solids from the imidazol-2-ylidenes 1 and CS2. 3 c reacts with bromine to give the cationic bromosulfane 4, whereas iodine forms the charge-transfer adduct 5. Oxidative coupling to the dicationic disulfane 6 is observed with excess of iodine. The X-ray structure analyses of 3b, 4, 5 and 6 are reported.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1994-1105/pdf

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