A new assembly of diiodine molecules at the 1,3-dimethylimidazole-2-thione (Me2ImS) template: crystal structure of (Me2ImS)2·(I2)5

Author:

Garau Alessandra1ORCID,Aragoni M. Carla1ORCID,Arca Massimiliano1ORCID,Caltagirone Claudia1ORCID,Demartin Francesco2ORCID,Isaia Francesco1ORCID,Lippolis Vito1ORCID,Pivetta Tiziana1ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, Cittadella Universitaria, 09042 Monserrato (CA), Italy

2. Dipartimento di Chimica, Università degli Studi di Milano, via Golgi 19, 20133, Milano, Italy

Abstract

The poly(I2) adduct [(Me2ImS)2·(I2)5] has been synthesised using a two-step process. The FT-Raman spectrum and MEP maps are discussed.

Funder

Regione Autonoma della Sardegna

Università degli Studi di Cagliari

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference63 articles.

1. V.Lippolis and F.Isaia , Charge-Transfer (C.-T.) adducts and Related Compounds, in Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium , ed. F. Devillanova and W.-W. du Mont , 2nd edn, 2013 , ch. 8.2, vol. 1, pp. 448–472

2. Practical crystal engineering using halogen bonding: A hierarchy based on calculated molecular electrostatic potential surfaces

3. Application of the Halogen Bond in Protein Systems

4. The reactions of sulfur and selenium donor molecules with dihalogens and interhalogens

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