Affiliation:
1. Comenius University in Bratislava, Faculty of Pharmacy, Department of Pharmaceutical Analysis and Nuclear Pharmacy , Odbojárov 10, SK-832 32 Bratislava , Slovak Republic
2. Comenius University in Bratislava, Faculty of Pharmacy, Toxicological and Antidoping Center , Odbojárov 10, SK-832 32 Bratislava , Slovak Republic
Abstract
Abstract
Structural data of cis-Pt(η2-P2L)(XL)2 (X = Ge or Te), cis-Pt(η2-P2L)(η2-X2L) (X = As, Ge or Te) and trans-Pt(η2-P,TeL)2 were classified and analyzed. The chelating ligands create varieties of metallocyclic rings, which open in the sequence: 83.1° (GeGeGe) < 83.8° (AsC2As) < 86.2° (PC2P) < 88.5° (PC2Te) < 89.7° (PC3P) ~ 89.7° (GeGe2Ge). The structural data are compared and discussed with the complexes of an inner coordination spheres Pt(η2-P2L)(XL)2 (X = O, N, CN, B, Cl, S, Se, Si, Br or I), Pt(η2-P2L)(η2- X2L) (X = O, N, S, Se or Si), and Pt(η2-P,SiL)2.
Subject
Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry
Cited by
4 articles.
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