Heterotridentate organodiphosphines in Pt(η3–P1X1P2)(Y) derivatives-structural aspects-Reference-Cited by-同舟云学术

Heterotridentate organodiphosphines in Pt(η3–P1X1P2)(Y) derivatives-structural aspects

Published:2021-07-22 Issue:0 Volume:0 Page:
ISSN:2191-0227
Container-title:Reviews in Inorganic Chemistry
language:en
Short-container-title:

Author:

Melník Milan¹,Mikuš Peter¹

Affiliation:

1. Comenius University in Bratislava , Odbojárov 10, SK-832 32 Bratislava , Slovak Republic

Abstract

Abstract This review covers over 30 examples of monomeric Pt(II) complexes of the types: Pt(η3–P1O1P2)(Y) (Y = PL, CL, OL), Pt(η3–P1N1P2)(Y) (Y = H, NL, CL, Cl, PL) and Pt(η3–P1P2N1)(Y) (Y = Cl). The heterotridentate donor ligands create 11 types of a couple chelate rings with common central atom O1 (η3–P1O1P2), N1 (η3–P1N1P2) and P2 (η3–P1P2N1). The most frequent is P1C2N1C2P2. Some cooperative effects between chelate rings and Y donor ligands were found and discussed. A degree of distortions of square-planar geometry about Pt(II) were also calculated.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/revic-2021-0011/pdf

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