Synthesis and characterization of a macrocyclic copper complex containing the 14-membered 1,3,5,8,10,12-hexaazacyclotetradecane unit-Reference-Cited by-同舟云学术

Synthesis and characterization of a macrocyclic copper complex containing the 14-membered 1,3,5,8,10,12-hexaazacyclotetradecane unit

Published:2017-01-12 Issue:2 Volume:72 Page:115-118
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Hakimi Mohammad¹,Mardani Zahra²,Moeini Keyvan³,Mohr Fabian⁴

Affiliation:

1. Chemistry Department, Payame Noor University, 19395-4697 Tehran, I.R. Iran , Fax: +98 511 8683001

2. Chemistry Department, Urmia University, 57561-51818 Urmia, I.R. Iran

3. Chemistry Department, Payame Noor University, 19395-4697 Tehran, I.R. Iran

4. Fakultät für Mathematik und Naturwissenschaften, Anorganische Chemie, Bergische Universität Wuppertal, 42119 Wuppertal, Germany

Abstract

Abstract In this work, a new macrocyclic copper complex, [Cu(ACE)(SCN)2]; ACE: 1,3,6,10,12,15-hexaazatricyclo[13.3.1.16,10]eicosane, was prepared and characterized by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. X-ray analysis of [Cu(ACE)(SCN)2] reveals an elongated octahedral geometry around the copper atom in a centrosymmetric CuN6 environment.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2016-0199/pdf

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