Affiliation:
1. Abteilung II fur Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule in Darmstadt, HochschulstraBe 4, D-6100 Darmstadt
Abstract
Abstract
The new compounds Ca9Mn4Bi9 and Ca9Zn4Bi9 crystallize in the orthorhombic system (Pbam) with
Ca9Mn4Bi9: a = 2242 ± 2 pm, b = 1256 ± 1 pm, c = 472 ± 1 pm,
Ca9Zn4Bi9: a = 2212 ± 2 pm, b = 1264 ± 1 pm, c = 465 ± 1 pm.
In the structure of the isotypic compounds there are Mn(Zn)Bi4-tetrahedra connected to chains by common corners. Four of these chains are connected by common comers to „Einervierfachketten“ in Liebau’s nomenclature for inosilicates.
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