Enhanced thermoelectric performance in the zintl antimonides (Ca,RE)9Cd4Sb9 (RE = rare-earth metal). Synergy between increased structural complexity and drive towards optimized chemical bonding
Author:
Funder
Office of Science
Basic Energy Sciences
U.S. Department of Energy
Publisher
Elsevier BV
Subject
Mechanical Engineering,General Materials Science
Reference41 articles.
1. Darstellung und kristallstruktur von Ca9Mn4Bi9 und Ca9Zn4Bi9/preparation and crystal structure of Ca9Mn4Bi9 and Ca9Zn4Bi9;Brechtel;Z. Naturforsch. B Chem. Sci.,1979
2. Probing the limits of the Zintl concept: structure and bonding in rare-earth and alkaline-earth zinc-antimonides Yb9Zn4+xSb9 and Ca9Zn4.5Sb9;Bobev;Inorg. Chem.,2004
3. Tuning the thermoelectric properties of Ca9Zn4+xSb9 by controlled doping on the interstitial structure;Wu;Chem. Mater.,2016
4. Sr9Mg4.45(1)Bi9 and Sr9Mg4.42(1)Sb9 : Mg-containing Zintl phases with low thermal conductivity;Zhang;Inorg. Chem.,2021
5. Exploring new Zintl phases in the 9-4-9 family via Al substitution. Synthesis, structure, and physical properties of Ae9Mn4–xAlxSb9 (ae = Ca, Yb, Eu);Liu;Inorg. Chem.,2020
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1. Synthesis and Crystal and Electronic Structures of the Zintl Phase Sr21Cd4Sb18;Solids;2023-11-17
2. The Electronic and Thermoelectric Transport Properties of Zintl Pnictides;Encyclopedia of Inorganic and Bioinorganic Chemistry;2023-09-29
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4. Exploiting the fraternal twin nature of thermoelectrics and topological insulators in Zintl phases as a tool for engineering new efficient thermoelectric generators;Journal of Materials Chemistry C;2023
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